Hexavalent chromium (Cr(VI)) compounds are a large group of chemicals with varying properties, uses, and workplace exposures. Traditionally, hexavalent chromium has also been used for passivation of electrolytically deposited copper foils used in printed circuit boards, Li-ion batteries and plasma screens. The dangerous compound made famous by the movie Erin Brockovich can occur naturally or through industrial pollution. It’s both odorless and tasteless, and it can be found naturally in rocks, soil, and plants. Hexavalent chromium plating is the traditional method of chromium plating (most commonly known as chrome plating) and can be used for decorative and functional finishes. But there's a lot of it about. NIOSH considers all Cr(VI) compounds to be occupational carcinogens. SUBPART 223.73 —MINIMIZING THE USE OF MATERIALS CONTAINING HEXAVALENT CHROMIUM. Chromium III is much less toxic than chromium (VI). Toxic carcinogen!" It turns out to be quite hard to discover much about it online, since the first ten thousand or so Google hits all say "Aaargh! Chromium 6, also known as hexavalent chromium, is the most toxic form of the metal chromium. Hexavalent chromium plating is achieved by submerging substrates into a bath of chromium trioxide (CrO 3) and sulfuric acid (SO 4). Chromium Compounds Hazard Summary Chromium occurs in the environment primarily in two valence states, trivalent chromium (Cr III) and hexavalent chromium (Cr VI). The respiratory tract is also the major target organ for Hexavalent chromium is harmful to the eyes, skin, and respiratory system. Chromium will control wood rot, sapstain and molds. Chromium in its hexavalent form has been used in industry for decades for metal plating to produce shiny, chrome-plated metal. My Favorites. Change Number/Effective Date: DFARS Change 11/30/2020 / 11-30-2020- Download Entire DFARS - HTML PDF. Hexavalent chromium shows up in predominantly three forms: 1) Trivalent Chromium, which occurs naturally as chrome ore and is also an essential nutrient for proper metabolism; 2) Metallic or Elemental Chromium, typically found in aerospace alloys; and 3) Hexavalent Chromium, typically from industrial processes like welding and thermal spray. These compounds have been used widely as corrosion inhibitors and in the manufacture of pigments, metal finishing and chrome plating, stainless steel production, leather tanning, and wood preservatives. Hexavalent chromium came to the attention of the general public through a lawsuit relating to contaminated groundwater filed against a well known energy company in 1993, in which the environmental campaigner Erin Brockovich — then working for a local law firm — played a major role. Hexavalent chromium [Cr(VI)] regulations. It is naturally found in rocks and may enter the groundwater by weathering of chromium 6-containing rocks or from industrial contamination. Chromium 6: Is used in pigments for textile dyes, paints, and inks Several chromium salts are used as wood preservative for example chromium(VI) salts. The layer is typically less than 15 nm (0.015 µm) and the chromium content amounts to 0.02-0.03 mg/m². Hexavalent chromium compounds are a group of chemicals that have useful properties, such as corrosion resistance, durability, and hardness. These salts are toxic to termites, beetles, and decay fungi. Wastewater containing chromium VI, used to protect a cooling tower from corrosion, had been … Not only does it impart a shiny appearance, but it also protects the underlying metal from rust and corrosion. Wood preservatives that contain chromated arsenicals (chromium, copper and arsenic) have been used since the 1940s. add this page. Exposure may occur from natural or industrial sources of chromium. 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